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Scientific Reports volume 13, Article number: 8188 (2023) Cite this article

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The mechanochemical ball milling followed by heating at 650 °C for 5 h successfully produced the single-phase Bi2VO5.5 powder. Catalytic activity for methylene blue dye degradation was investigated. Raman spectroscopy and X-ray diffraction were used to confirm the phase formation. The sample's charge carrier transportation behavior was ascertained using time-dependent photocurrent analysis. The piezo-photocatalysis experiment yielded a 63% degradation efficiency for the ball-milled Bi2VO5.5 sample. The pseudo-first-order kinetics of the piezo-photocatalytic dye degradation are discerned, and the significant k value of 0.00529 min−1 is achieved. The scavenger test declares the h+ radical is the predominant active species during the piezo-photocatalysis experiment. Vigna radiata seeds were used in a phytotoxicity test to evaluate the germination index. The mechanochemical activation method facilitates reactions by lowering reaction temperature and time. The effect of improved piezo-photocatalytic efficiency on the ball-milled Bi2VO5.5 powder is an unexplored area, and we have attempted to investigate it. Here, ball-milled Bi2VO5.5 powder achieved improved dye degradation performance.

Currently, the rapid rate of industrialization has pushed human society into a new era where the conservation of the environment is a major concern. People have started to realize the need for environmental conservation by finding better ways to address environmental damage1. Organic pollutants that are very frequently employed in food, pharmaceutical, printing, dyeing, and other industries include colors and antibiotics2. Organic dyes are a significant component of industrial wastewater as textile industries discharge them in large quantities directly into aquatic sources causing serious environmental risks and are harmful to human health as well3. Organic pollutants being carcinogenic and poisonous deteriorate aquatic, animal, and human health4. Numerous studies have been conducted and published in the literature to create standard methods for removing pollutants from industrial wastewater5,6. Conventional methods of water purification, such as coagulation, adsorption, ultra-filtration, and microbial degradation, have been the norm for treating wastewater until recently7. However, these techniques have the flaw of having poor removal efficiency, the secondary pollutant that needs further treatment, and difficulty in eliminating contaminants with low concentrations7,8. Therefore, it became vital to create efficient and ecologically acceptable processes to break down these organic contaminants.

Multiple physical, chemical, and biological processes are now used for the treatment of textile wastewater9. Tested and affordable technology is photocatalysis and piezocatalysis10,11. They are considered green alternatives due to their potential to be environment friendly and eliminate organic contaminants from aqueous solutions with high efficiency4,12. In semiconductor photocatalysis, improvement of the photocatalyst is required to enhance their abilities to absorb light while facilitating the separation of different charge carriers13,14. Semiconductor photocatalysts showed remarkable potential in photocatalysis because of their unique band structures, mobility, and excellent separation of photogenerated charge carriers15. Benefits of photocatalysis include the ability to oxidize toxins at room temperature at low concentrations, the reduction of secondary pollutants, low cost, and non-toxicity which makes it appropriate for the degradation of the contaminants16,17. Anatase TiO2 is currently the most preferred photocatalyst due to its higher oxidizing power, lower price, and excellent chemical stability18,19. Owing to its broad bandgap (3.20 eV) and the relatively small lifespan of photo-induced carriers, TiO2 has poor quantum efficiency since it can only absorb the UV part of the sun's rays1,18. Therefore, it's critical to create an effective visible-light-active photocatalyst. In addition to photocatalysis, ultrasonic vibration-induced piezocatalysis can also be utilized alone or in combination for wastewater treatment20,21. There has been an immense search to create new photocatalysts that respond to visible light more effectively. Bi-based semiconductors have garnered considerable attention owing to their novel characteristics and easy availability of raw materials7,22. In presence of the hybridized Bi (6s) and O (2p) valence bands, many oxides containing Bi3+ have photocatalytic characteristics23. As new photocatalytic materials, bismuth-based substances such as BiVO4, Bi2WO6, Bi2MoO6, CaBi2O4, BiNbO4, and Bi2VO5.5 have been reported1,24,25,26,27. The bismuth-based oxides, like bismuth vanadate, possess spectacular features such as corrosion resistance, nontoxicity, ferroelasticity, and ionic conductivity28,29. In contrast to the majority of ferroelectric materials, bismuth vanadate (Bi2VO5.5, (BV)) exhibits simultaneous high ionic mobility and polar responses, two properties that are typically incompatible30,31. There are numerous applications for it, including catalysts, solid electrolytes, gas sensors, and positive electrode materials for lithium rechargeable batteries32,33,34. Bi2VO5.5 can be produced using several techniques, including sol–gel, co-precipitation, solid-state reaction, and microwave33,35,36. Piezoresponsive behavior is a result of the non-centrosymmetric orthorhombic structure of BV37,38. The material underwent spontaneous polarization due to discrete stable polarization that was induced by the non-centrosymmetric unit cell39. The resulting surface polarization leads to band bending and space charge regions39. The standard formula for Bi2VO5.5 is (Bi2O2)2+ (An−1BnO3n+1)2−, where B stands for hexa-, tetra-, and pentavalent ions, n for the number of perovskite blocks squeezed between layers of Bi2O2, and A for di-, tri-, and mono-valent ions40,41. BV has a layered structure like BiVO442. Due to its low bandgap, BV is used across a broad visible light absorption range42. The traditional ceramic synthesis method requires high temperature and more reaction time43. The Mechanochemical activation method facilitates reactions by lowering reaction temperature and time without changing stoichiometry43. It has been effectively used to speed up compound formation and phase transitions, as well as to improve the physiochemical properties of novel materials43,44. Furthermore, the catalyst's surface area is a crucial component. The catalyst nanoparticle's wide surface area allows for the adsorption of dye molecules that are sufficient for photon capture and electron–hole pair production, which can improve photocatalytic activity45,46. Small particle-size material has been reported to be produced via sol–gel, co-precipitation, microwave, and mechanochemical ball milling (MBM) activated processes33,47. Due to their vast surface area, small particle size is advantageous in enhancing catalytic efficiency45. Xie et al.48 successfully degraded methylene blue (MB) using Au nanoparticles deposited on Bi2VO5.5 with an efficiency of 85.2%. Jianmin Wang et al. employed a BiVO4/Bi2VO5.5 nanostructure to degrade methylene orange (MO) by 95% in the presence of visible light42. Bi2VO5.5/Bi2O3 composite films were used by Xie et al. to achieve 89.97% MB dye degradation efficiency under simulated sunshine 1.

In a similar spirit, this study presents the findings of a mechanochemical ball milling (MBM) synthesis approach used to produce the intriguing Bi2VO5.5 oxide. Using the MBM synthesis approach to synthesize powdered BiVO4 sample, we recently reported an 81% degradation efficiency of MB dye using piezo-photocatalysis44. Utilizing a Bi2VO5.5 powdered sample that has not been synthesized through a ball mill, we were able to degrade MB dye to attain an efficiency of 82% using piezo-photocatalysis34. Bi2VO5.5 powder made using the MBM process has not yet been investigated for piezo-photocatalytic use. The synergetic effect of photocatalysis and piezocatalysis would attain high disintegration efficiency in a shorter time as compared to the bare photocatalysis and bare piezocatalysis approach. With respect to the meta-stable elevated energy state, the reduction in particle size that occurs during milling causes defects and micro-stress. BV is therefore subjected to post-annealing treatment to eliminate the generated defects34,49. The effect of improved piezo-photocatalytic efficiency on the ball-milled BV powder is an unexplored area, and we have attempted to investigate it here. Dye degradation efficiency and time for treatment would both improve with the ball-milled powder's application in industrial wastewater treatment.

The mechanochemical ball milling (MBM) method is a productive way to create materials with submicron and nanoscale dimensions. Repeated welding and fracture ensure that each material is subjected to a solid-state reaction that results in the final synthesis of powder material. With this technique, submicron-sized powdered material of the right stoichiometry is obtained by alloying the current chemical components. The MBM synthesis method produced BV powder is depicted in Fig. 1. V2O5 and Bi2O3 oxide powders were combined in a 250 ml tungsten carbide jar according to the stoichiometric molar ratio. In order to mill the material, we used 10 tungsten carbide balls, each of which was 20 mm in diameter. For 17 h duration at 300 rpm speed, a Retsch planetary ball mill (PM100) configuration was employed for the grinding at ambient temperature. After every 30 min, a 5-min break was provided to enable the system to cool. Particle size reduction was further induced during the 26-h wet milling operation at 300 rpm using a specific weight ratio of 1:20:0.5 for the BV powder, yattria stabilized zirconia (YSZ) balls, and ethanol. After separating the YSZ balls, the powders obtained were subjected to a 5-h annealing process at 650 °C to remove any induced defects that may have developed during uninterrupted ball milling. We obtained the ball-milled Bi2VO5.5 (BV) powders after annealing. A distinct Bi2VO5.5 (BiV) that was not subjected ball mill was prepared by grinding using mortar-pestle through utilizing oxide powders of V2O5 and Bi2O3 in the correct stoichiometric molar ratio to show the comparison in photocatalytic activity. To confirm the Bi2VO5.5 phase, the powders were ground with the aid of a mortar and pestle and then they were calcined at 750 °C for 8 h. The X-ray diffraction method is utilized to establish the BiV phase formed and has been confirmed34. Additionally, a peculiar, not ball-milled Bi2VO5.5 (NBM BiV) was synthesized by combining the oxide powders of V2O5 and Bi2O3 in the correct molar ratios. The powders were crushed in a mortar and pestle before being calcined for 5 h at a temperature of 650 °C. This was done to understand whether the not ball-milled sample synthesized at a reduced temperature could attain the proper phase formation.

The process involved in making the BV powder.

The resulting BV powdered samples' phases were determined with the use of the X-ray diffraction technique (XRD, Rigaku diffractometer, Japan). The 2°/min scan rate was applied on the sample powder across a 10–65° 2θ angle range. Raman spectroscopy was utilized to analyze the material's structure and bonding. Using a 10% power 532 nm laser and 600 gratings to scan over the material across the 100–1300 cm−1 range, the Raman spectra were obtained through HORIBA (LabRAM HR Evolution, Japan) spectrometer. The KBr pellets were used as the matrix for a Fourier transform infrared spectroscopy (FTIR) examination performed with a Perkin Elmer spectrum RX I spectrophotometer. Accurate information on the microstructures and surface morphologies of the materials was obtained using a Nova Nano SEM-450 field emission scanning electron microscope (FE-SEM). Energy dispersive spectroscopy (EDS), which is integrated with SEM, was employed to comprehend the compositional elements in the BV sample. X-ray photoelectron spectrometer (Nexsa) equipment was used to evaluate the binding energy and chemical state of the produced BV sample. The UV–visible spectrophotometer (SHIMADZU) was used to evaluate the absorbance peak intensity.

The generated BV sample's current–time profile was recorded using an electrochemical workstation (AUT86543 Metrohm Autolab B.V.). A platinum wire was used as the counter electrode, and an Ag–AgCl wire was used for both the working and reference electrodes in the three-electrode arrangement. A source of visible light was given by two Havells Company each of 15 W bulbs. To record the photocurrent response, the visible light source went through a few ON and OFF cycles. The used electrolyte was a phosphate-buffered saline solution of 0.1 M concentration. The working electrode was made by mixing 1 mL of ethanol, 5 mg of catalyst, and 20 µL of Nafion solution. After being well mixed together by ultrasonication for 30 min, the resulting catalyst ink was applied as a surface coating on the cleaned glassy carbon electrode with ~ 10 µL of catalyst ink. Before employing the electrode as the working electrode, it was confirmed that the coat had dried properly.

Diffuse reflectance spectroscopy (DRS) was employed to ascertain the bandgap of the synthesized sample. According to the literature, the direct bandgap was determined by converting the absorption spectra acquired from the DRS into Tauc's plot (a plot between E vs \(\left( {\alpha E} \right)^{2}\))50.

To evaluate the efficacy of the BV powdered sample in the photocatalytic experiment, we measured the degradation of MB dye in the presence of visible light. Typically, 0.2 g (g) sample was utilized in the photocatalysis experiment. The adsorption–desorption saturation of the dye was obtained before the start of the photocatalytic evaluation. The first starting dye was swapped out by a new 20 ml dye at a concentration of \(\sim\) 5 mg/L when the adsorption equilibrium was acquired. Two light bulbs were used to provide visible light illumination for the BV sample immersed inside the dye solution (Havells company, each of 15W power). A distance of around 12 cm was set between the sample and the incoming light source. Throughout the experiment, the sample was continuously stirred at a 500 rpm speed. The adsorption peak intensity was used to assess the photocatalytic activity. To maintain a constant volume throughout, the test material was carefully replenished back into the beaker after each regular period of acquisition and evaluation of absorbance. For comparison, a photocatalysis evaluation was conducted with the same parameters using a 0.2 g BiV sample that had not been synthesized through a ball mill. According to Eq. (1), the degradation rate percentage of the MB dye was established51.

where \({\text{C}}_{{\text{o}}}\) and \(C\) stand for the amount of MB dye present before and following the passage of time ‘t’, respectively.

The MB dye degradation in ultrasonic vibration was utilized as a parameter to assess the piezocatalytic efficacy of the powdered BV. Typically, 0.2 grams (g) sample was utilized in the catalysis assessment. The adsorption–desorption saturation of the dye was obtained before the start of the piezocatalysis evaluation. When adsorption saturation is reached, the already used dye is swapped out by a new 20 ml dye at a concentration of \(\sim\) 5 mg/L. The BV powder added to the dye solution was then put to ultrasonic vibration received from an ultrasonicator (120 W, 40 kHz). To prevent the dye solution from heating up during ultrasonication, the water in the ultrasonicator was changed after every 15 min because it served as the medium for the process. This experiment was carried out in complete darkness. To maintain a constant volume throughout, the test material was carefully replenished back into the beaker after each regular period of acquisition and evaluation of absorbance. For comparison, a piezocatalysis evaluation was conducted with the same parameters using a 0.2 g BiV sample that had not been synthesized through a ball mill.

The MB dye degradation in the synergetic indulgence of ultrasonic vibration along with visible light illumination was utilized as a parameter to assess the piezo-photocatalytic efficacy of the powdered BV. The BV sample weighing 0.2 g was taken to perform the catalysis evaluation. The adsorption–desorption saturation of the dye was accurately reached before beginning the piezo-photocatalysis evaluation. When adsorption saturation is reached, the already used dye is swapped out by a new 20 ml dye at a concentration of \(\sim\) 5 mg/L. The dye solution and BV powder sample were then exposed to both visible light irradiation from two Havells Company bulbs (each with a 15 W power output) and ultrasonic vibration received from an ultrasonicator (120 W, 40 kHz). To prevent the dye solution from heating up during ultrasonication, the water in the ultrasonicator was changed after every 15 min because it served as the medium for the process. To maintain a constant volume throughout, the test material was carefully replenished back into the beaker after each regular period of acquisition and evaluation of absorbance. For comparison, a piezo-photocatalysis evaluation was conducted with the same parameters using a 0.2 g BiV sample that had not been synthesized through a ball mill.

The XRD scans of the synthesized BV, BiV, and NBM BiV powder samples are shown in Fig. 2. The obtained XRD patterns of BV and BiV show that all the diffracted peaks agree with the orthorhombic Bi2VO5.5 standard JCPDS reference file (File No. 42-0135). BV and BiV formed in a single phase without the existence of any secondary phase. Bi2VO5.5 phase is present in NBM BiV, although secondary peaks of V3O5, V2O5, V2O4, and Bi2O3 are also present at 18.8, 24.2, 26.8, and 27.9 degrees, respectively. In contrast to the 24-h annealing at 1020 K previously described, this study synthesizes single-phase Bi2VO5.5 more quickly31. The mechanochemically ball milling (MBM) approach produced tiny particles that helped in synthesizing single-phase Bi2VO5.5 viable at 650 °C in just 5 h. Further experimental tests are likely to exclude the NBM BiV powdered sample due to the presence of an additional phase and the inability to synthesize the powder using the mortar and pestle method within 5 h at 650 °C.

XRD results for BV, BiV, and NBM BiV powders.

The Raman bands linked to the fabricated BV sample are shown in Fig. 3a. The Raman spectra were examined between 350 and 1300 cm−1. The major Raman bands were found at the wavelengths 372, 653, 768, 852, and 926 cm−1. These obtained bands are consistent with previously published studies9,52. While the bands at 768 and 653 cm−1 reveal the doubly coordinated (V–O–V) oxygen atom, the band observed at 372 cm−1 demonstrates the symmetric vibrational mode bending of the V–O bonds9,52. Short-range vibrational V–O bonds are demonstrated by the band obtained at 852 cm−1, while the weak mode at 925 cm−1 represents the V4+  = O unit. The availability of vanadium in the mixed valence state of + 4 and + 5, causes this weak vibrational mode represented as the V4+=O signature52.

The BV sample's (a) Raman spectrum and (b) FTIR spectrum.

Material's functional group change is understood by the FTIR spectroscopic analysis of the BV sample shown as in Fig. 3b. In this case, significant IR bands are present at 832, 766, 715, 610, and 529 cm−1. The V–O bond asymmetric stretching is shown by the peak at 832 cm−1 while the V–O bond symmetric vibration stretching is shown by the peak at 766 and 715 cm−153,54. There are peaks visible at 613, and 529 that show the (O–V–O) vanadate anion deformation55,56.

The SEM micrographs have been utilized to illustrate the sample's surface morphology as displayed in Fig. 4. Figure 4a–c provides clear proof of the presence of the BV sample's irregular-shaped grains. The not ball milled BiV sample's irregular shaped morphology is shown in Fig. 4d. We effectively decreased the particle size to the submicron range using the ball milling approach, as shown by the SEM micrographs. Figures 4c,d show the difference in particle size between the ball-milled Bi2VO5.5 (BV) sample and the not ball-milled Bi2VO5.5 (BiV) sample. For the BV sample, EDS elemental color mapping was carried out to achieve accurate phase identification. Figure 4e–f displays the chosen area of mapping and the presence of the O, V, and Bi elements.

SEM photographs of (a–c) BV sample, (d) BiV sample, and (e–f) EDS elemental color mapping assessment of BV.

To ascertain the elements’ chemical states, the BV powdered sample underwent an XPS examination. The XPS spectra that correspond to the V2p, O1s, and Bi4f scans are shown in Fig. 5a–c. Each of the asymmetric Bi4f7/2 and Bi4f5/2 components of the Bi4f spectrum was initially separated into their respective Bi2+ and Bi3+ components. Two peaks, at 157.3 and 163.7 eV, are compatible with the Bi2+ oxidation state, while two more, at 158.8 and 164.1 eV, are consistent with the Bi3+ oxidation state57,58. Each of the V2p3/2 and V2p1/2 components of the V2p spectrum were initially separated into their respective V4+ and V5+ components. The V5+ oxidation state is shown by peaks at 516.4 and 524.2 eV, whereas the V4+ oxidation state is indicated by peaks at 517.3 and 523 eV59. Asymmetric O1s spectra were also first split into OL and OA sub-components. The OL and OA symbols represent oxygen vacancies and lattice oxygen (O2− oxidation state), respectively57. Intrinsic defects introduced during production and heat treatment lead to localized oxygen vacancies. Bi3+ and V5+ are converted to Bi2+ and V4+, respectively, as a result of the bonded additional charge in the form of electron pairs surrounding the V and Bi atoms and in the vacant area. Consequently, we confirm the occurrence of Bi2+ and V4+ in addition to the previously documented Bi3+ and V5+60.

(a–c) The XPS spectra acquired for V2p, Bi4f, and O1s.

Figure 6a depicts a time-dependent photocurrent study of a powdered BV sample, which was used to determine the charge carrier transportation behavior of the sample. BV achieves a low dark current density of (~ 2.8 µA/cm2) before dye degradation, and it shows an increased photocurrent density of (~ 6.5 µA/cm2) when exposed to visible light. We were able to get a ratio of about 2.3 times between visible light and dark current as an outcome. Separation of the photogenerated charge carriers is facilitated by the formation of high photocurrent density. The BV sample's photocurrent response may be inverted, as shown by repeating the photocurrent density at each irradiation intensity61,62.

The BV sample's (a) Time-dependent photocurrent response (b) The absorbance spectrum (c) Tauc's plot.

Figure 6b depicts the diffuse reflectance spectrum (DRS) measured from the BV powdered sample. It displays the ball-milled BV sample's acquired optical absorption edge. The examined bandgap value of the BV sample is shown as 2.15 eV in Fig. 6c. Since the bandgap of BV is within the visible spectrum, the photocatalysis experiment may be carried out using visible light.

The photocatalysis experiment for the BV powder was evaluated by MB dye degradation, and the findings are shown in Fig. 7a. The dye's precise adsorption–desorption saturation was obtained before the start of the photocatalytic evaluation. Figure 7a shows that as the time duration of visible light irradiation was increased for the purpose of evaluating photocatalytic evaluation, the UV–visible absorption peak spectra of the MB dye dropped. The decreasing peak intensity with longer exposure time is proof that the polluting dye solution has become discolored. The \(\frac{C}{{C_{o} }}\) versus time plots obtained for photocatalysis evaluation with BV, BiV, and without the usage of BV samples (control) are shown in Fig. 7b. Without a sample, photolysis caused the control dye to degrade by ~ 12% after 180 min when exposed to visible light. In 180-min visible light exposure, the MB degradation efficiencies of the BV and BiV samples were ~ 29% and ~ 17%, respectively. In comparison to the control sample, the dye degradation efficiency of the BV and BiV samples improved by 17% and 5%, respectively. The variation in particle size between the BV and BiV samples, which has also been shown by SEM micrographs, is the cause of the discrepancy in the photocatalytic effectiveness reached by the two samples. We demonstrated that ball milling improved the catalytic performance by showing that BV's degradation efficiency was 12% higher than that of not ball mill synthesized BiV sample.

(a) Absorption spectra changes during photocatalytic testing with BV sample (b) \(\frac{C}{{C_{o} }}\) versus time plots for photocatalytic testing with BV, BiV, and without samples.

The BV powder piezocatalysis experiment was evaluated by monitoring the MB dye degradation, and the findings are displayed in Fig. 8a. As shown in Fig. 8a, the reduction in the MB dye's absorption peak spectrum with an increase in ultrasonication time served as proof that MB dye degradation occurred under ultrasonication. The decolorization of the pollutant solution is supported by the decreasing peak spectra with time. The \(\frac{C}{{C_{o} }}\) versus time data obtained for piezocatalysis evaluation with BV, BiV, and without the use of BV samples (control) are shown in Fig. 8b. Water bubbles that contain entrapped gases and water vapor form, grow and collapse as a result of the ultrasonication process63. This activity generates a local hot zone where temperature increases up to 4000–5000 K63,64. These localized hot zones promote the thermolytic breakdown of water, resulting in the generation of ·OH radicals. These produced ·OH radicals accelerate the degradation of MB dye. Sonolysis is the term used in literature to describe the entire phenomenon65. To prevent the dye solution from heating up during ultrasonication, the water in the ultrasonicator was changed after every 15 min because it served as the medium for the process. In 180 min of ultrasonication, the control dye experienced 13% MB dye degradation in the absence of any sample. In the 180-min piezocatalysis experiment, the MB dye degradation efficiencies of the BV and BiV samples were ~ 32% and ~ 20%, respectively. In comparison to the control sample, the dye degradation efficiency of the BV and BiV samples improved by 19% and 7%, respectively. The variation in particle size between the BV and BiV samples, which has also been shown by SEM micrographs, is the cause of the discrepancy in the piezocatalytic effectiveness reached by the two samples. We demonstrated that ball milling improved the catalytic performance by showing that BV's degradation efficiency was 12% higher than that of not ball mill synthesized BiV sample.

(a) Changes in absorption spectra during piezocatalytic testing with BV sample (b) \(\frac{C}{{C_{o} }}\) versus time data obtained for piezocatalytic testing with BV, BiV, and without sample.

The BV powder piezo-photocatalytic experiment was evaluated by monitoring the MB dye degradation, and the findings are displayed in Fig. 9a. The dye's precise adsorption saturation was obtained before starting the piezo-photocatalysis evaluation. For evidence of MB dye degradation by piezo-photocatalysis, we tracked the time-dependent shift in the dye's absorption peak spectra, as shown in Fig. 9a. The decolorization of the pollutant solution is supported by the decreasing peak spectra with time. Water bubbles that contain entrapped gases and water vapor form, grow and collapse as a result of the ultrasonication process. This activity generates a local hot zone where temperature increases up to 4000–5000 K63,64. These localized hot zones promote the thermolytic breakdown of water, resulting in the generation of ·OH radicals. These produced ·OH radicals accelerate the degradation of MB dye66. To prevent the dye solution from heating up during the piezo-photocatalysis experiment, the water in the ultrasonicator was changed after every 15 min because it served as the medium for the process. The \(\frac{C}{{C_{o} }}\) versus time chart obtained for piezo-photocatalysis evaluation of BV, BiV, and without the use of any sample (control) are shown in Fig. 9b. In a 180-min piezo-photocatalysis experiment, the control dye degrades by ~ 19% without the use of any samples. In 180 min of piezo-photocatalysis assessment, the MB degradation efficiencies of the BV and BiV samples were ~ 63% and ~ 28%, respectively. In comparison to the control sample, the dye degradation efficiency of the BV and BiV samples improved by 44% and 9%, respectively. The variation in particle size between the BV and BiV samples, which has also been shown by SEM micrographs, is the cause of the discrepancy in the photocatalytic effectiveness reached by the two samples. We demonstrated that ball milling improved the catalytic performance by showing that BV's degradation efficiency was 35% higher than that of not ball mill synthesized BiV sample. The degradation efficiency of MB dye by piezo-photocatalysis, piezocatalysis, and photocatalysis on the BV sample is shown in Fig. 9c. During the evaluation of photocatalysis, piezocatalysis, and piezo-photocatalysis, BV powdered sample achieved the MB dye degradation efficiency of 29%, 32%, and 63%, respectively. It is evident that piezo-photocatalysis combination effects resulted in higher degradation efficiencies than individual piezocatalysis and individual photocatalysis studies were able to produce. The usage of a BV powdered sample demonstrated a 34% and 31% improvement in degradation performance during the piezo-photocatalysis as compared to the results of the individual photocatalysis and piezocatalysis experiment respectively. Because of the altered band structure brought on by the internal electric field, piezo-photocatalysis assessment results in greater utilization of the produced charge carriers67,68. Additionally, current polarization effectively separates charge carriers, reducing the likelihood of charge recombination67,69. Therefore, the piezo-photocatalysis dual effect may prove to be a useful strategy for increasing photocatalytic and piezocatalytic efficiency. During the investigation of the piezo-photocatalysis assessment, scavengers like isopropanol (IPA), p-benzoquinone (p-BQ), and ethylenediaminetetraacetic acid (EDTA) were added separately to the dye solution to bind the active radical species such as the hydroxyl radical (·OH), superoxide radical (\(^{ \cdot } {\text{O}}_{2}^{ - }\)), and holes (h+) respectively70. Figure 9d shows how the piezo-photocatalysis assessment using the BV sample has been significantly impacted by the EDTA scavenger that preferably scavenges holes (h+). Based on results from a scavenger assay, the principal active species in piezo-photocatalytic dye degradation are holes (h+).

(a) Absorption spectra changes during photocatalytic testing with BV (b) \(\frac{C}{{C_{o} }}\) versus time obtained for photocatalytic testing with BV, BiV, and without sample (c) evaluation of piezo-photocatalysis, piezocatalysis, and photocatalysis with BV (d) different scavengers effects examined using BV powders during piezo-photocatalytic analysis.

Figure 10a displays the \(\frac{C}{{C_{o} }}\) versus time plots acquired during the piezo-photocatalysis evaluation utilizing BV powdered material at various dye concentrations (5, 10, and 15 mg/L). Figure 10b displays the − ln \(\left( {\frac{{\text{C}}}{{{\text{C}}_{{\text{o}}} }}} \right)\) versus time acquired during the piezo-photocatalysis assessment utilizing BV sample at different dye concentrations. The pseudo first-order kinetics described by Eq. 2 governs the piezo-photocatalytic degradation reaction in this instance71,72.

here "k" stands for the kinetic rate constant determined by the \({\text{ln}}\frac{{\text{C}}}{{{\text{C}}_{{\text{o}}} }}\) versus time ‘t’ linear chart's slope. The eminent k value of 0.00529 min−1 is attained here at a dye concentration of 5 mg/L and experiences a decrease in the value of k with enhancement in dye concentration. The obtained kinetic rate constants for varying dye concentrations of 5, 10, and 15 mg/L were 0.00529, 0.00218, and 0.00113 min−1, respectively. Figure 10c presents the graph between the kinetic rate constant "k" and the various MB dye concentrations (5, 10, and 15 mg/L). The MB dye calibration curve is displayed in Fig. 10d. This curve was generated by measuring the distinctive peak absorbance intensity of MB dye at varied concentrations (0, 5, 10, 15, and 20 mg/L). Figure 10d demonstrates a linear relationship between absorbance and concentration. With the use of this curve, the absorbance intensity value of the dye solution used in the catalysis experiment may be determined. Some detailed study can be found in supplementary data S1.

(a) \(\frac{C}{{C_{o} }}\) versus time chart for piezo-photocatalytic evaluation at varying dye concentration (b) − ln \(\left( {\frac{{\text{C}}}{{{\text{C}}_{{\text{o}}} }}} \right)\) versus time chart for piezo-photocatalytic evaluation at varying dye concentrations (c) plot across the kinetic rate constant ‘k’ versus concentration of MB dye (mg/L) and (d) calibration curve of MB dye.

To investigate the sustainability, reusability, and appropriateness of the cleansed wastewater following the piezo-photocatalysis assessment, a simplified germination index (GI) test had been conducted, wherein seed germination along with their complete growth had been assessed. Vigna radiata seeds were obtained from Dr. Rajendra Prasad Central Agricultural University, Bihar. All the experiments were performed following relevant guidelines. Each of the three vials contained 10 Vigna radiata seeds, which received daily 0.5 ml each of untreated, treated, and distilled water sprinkling. The evaluation of the test was completed over seven days in India's IIT Mandi, wherein the average outside temperature noted was 30 °C. Figure 11a–c shows seed growth in three different scenarios: dye water before being subjected to piezo-photocatalysis, dye water after piezo-photocatalysis, and distilled water. It was shown that the majority of hurdles towards the growth of seed were associated with untreated 5 mg/L dye, whereas seed growth under the influence of the treated water is non-toxic73. However, edible plants require further protection, and any negative effects must be effectively managed. As an alternative to watering edible plants, we propose using this treated wastewater for playground irrigation74. The need for water will thereby be partially reduced. Results for phytotoxicity are displayed in Fig. 11d. Emino et al. have proposed three classes for substances based on GI values: strong phytotoxicity \(\left( {{\text{GI}} < 50\% } \right),\) moderate phytotoxicity \((50{\text{\% }} < GI < 80\% ),\) and no phytotoxicity \(({\text{GI}} > 80\% )\)72,75. According to the findings, whereas untreated dye has a high degree of toxicity, treated water has a moderate level of toxicity72,75. Here, a piezo-photocatalysis evaluation of the treated water utilized for the germination of the seed had only achieved 63% of dye degradation efficiency. By increasing the catalytic load, lengthening the catalytic time span, and lowering dye concentration, it is also possible to achieve 100% dye purification efficiency, which would further increase the germination index21,76.

Effect of MB dye on the development of Vigna radiata seeds over the course of 7 days. The evaluation was conducted using (a) 5 mg/L MB dye (b) treated wastewater (c) distilled water (d) Analysis of the germination index on 2 samples taken after 0 and 3 h after the piezo-photocatalysis experiment.

A description of the mechanism incurred by BV while the degradation pathway of MB dye under the photocatalysis, piezocatalysis, and piezo-photocatalysis studies is shown in Fig. 12a–c. The mechanism of photocatalysis is shown in Fig. 12a, wherein the synthesized BV phase forms electron–hole pairs in response to light stimulation. Superoxide radicals (\({\text{O}}_{2}^{ \cdot - } )\) are produced when electrons react with adsorbed oxygen, whereas hydroxyl radicals \({\text{(OH}}^{ \cdot } )\) are produced when holes oxidize the adsorbed water. Reactive oxidizing species (ROS) include species like (\({\text{O}}_{2}^{ \cdot - } )\) and \({\text{(OH}}^{ \cdot } )\), which degrade MB dye into innocuous end products. As a result, photocatalytic activity occurs4,44.

Mechanism incurred by BV during the evaluation of (a) photocatalysis (b) piezocatalysis (c) piezo-photocatalysis.

The piezocatalysis mechanism is presented in Fig. 12b. The cavitation process creates local hot spots, which exert forces on the BV surface to cause local strain66. The strain induced by ultrasonication leads to the formation of polarization charges (an internal electric field) on the surface of BV. Internal electric field influence causes the free electron–hole pairs to shift to the opposite polarity, aiding in the dissociation of e−–h+ pairs77,78. As a result, the BV surface has increased free charge accumulation since the probability of charge carrier recombination is suppressed69,79. Although there is still disagreement over the potential charge carriers source during the ultrasonication process, it is thought that sonoluminescence (during ultrasonication, light is produced at a wavelength of 375 nm) and heat rise due to hot spot creation may be the source80,81. Ultrasonication with phenomena like polarization may have a synergistic effect. Additionally, polarization-induced band bending aids in the transport of e− and h+ to the BV surface. These are not photogenerated e− and h+ because the piezocatalysis occurs in the dark. Superoxide radicals (\({\text{O}}_{2}^{ \cdot - } )\) are produced when electrons interact with adsorbed oxygen, whereas hydroxyl radicals \({\text{(OH}}^{ \cdot } )\) are produced when holes oxidize the adsorbed water. These ROS also contribute to the formation of innocuous end products as MB dye degrades44,63,64. Consequently, piezocatalytic activity occurs.

The piezo-photocatalysis mechanism is presented in Fig. 12c. The valence band (VB) electrons are stimulated by visible light to move into the conduction band (CB), while the VB holes are left behind, creating electron–hole pairs in the BV phase82. Although there is still disagreement over the charge carriers source during the ultrasonication process, it is thought that sonoluminescence (during ultrasonication, light is produced at a wavelength of 375 nm) and heat rise due to hot spot creation may be the source80,81. Ultrasonication with phenomena like polarization may have a synergistic effect. In piezo-photocatalysis, thermally excited holes and electrons predominate over photo-excited ones, which are in minor concentration. As a result, the addition of ultrasonication and visible light improves the concentration of free charges on the surface of the semiconductor catalysts83. The stress created during ultrasonication induces polarization charges on the BV surface. Local hot spots are formed as a consequence of the cavitation process, and these hot spots act on the BV surface to produce local strain63,64. A positive polarization charge is created at the surface by a ferroelectric domain whose orientation is from the bulk to the surface, whereas a negative charge is produced by a domain whose orientation is from the surface to the bulk. By doing so, an electric field within the BV can be created. Positive and negative polarization charges on the BV will attract photogenerated electrons and holes, accordingly84. The energy band is shifted downward at the positive polarization charge side and shifted upward at the negative polarization charge side, as shown in Fig. 12c. As a result of band bending brought on by polarization, photo-excited electrons are further moved to a lower energy level whereas the photogenerated holes in the VB are moved to an elevated energy level85. The dominant polarization prevents recombination between electrons and holes by increasing the space between the charge carriers, which sends electrons and holes in opposite directions78. As a result, the BV surface will have more electrons and holes available, which will increase the generation of radicals. It is energetically more desirable for both holes and electrons to take part in redox processes. Thus, the catalytic redox reaction is improved, speeding up the efficiency of dye degradation. Electrons reacting with adsorbed oxygen create superoxide radicals (\({\text{O}}_{2}^{ \cdot - } )\), while hydroxyl radicals \({\text{(OH}}^{ \cdot } )\) are produced when holes oxidize the adsorbed water. These ROS also contribute to the innocuous end products formed as MB dye degrades44,63. The enhanced catalytic degradation can be traced back to the link between polarization potential and photoexcitation effects, which facilitates photogenerated electron–hole pairs separation and effectively suppresses carrier recombination. Consequently, piezo-photocatalytic activity occurs.

The ball-milled Bi2VO5.5 powder was investigated to achieve improved piezo-photocatalytic efficiency after it was produced through mechanochemical ball milling synthesis at 650 °C for 5 h. By successfully segregating charge carriers, the catalyst efficiently utilized the synergetic impact of visible light irradiation along with ultrasonic vibration for enhanced dye degradation. The effectiveness of dye degradation achieved through piezo-photocatalysis, piezocatalysis, and photocatalysis was examined, along with the process of degradation. The piezo-photocatalysis assessment obtains a dye degradation efficiency of ~ 63% using a Bi2VO5.5 powdered sample. The dye disintegration follows a pseudo-first-order kinetic and reaches a maximum k value of 0.0053 min−1. Reduced particle size attained through the ball milling synthesis of the Bi2VO5.5 sample along with synergetic piezo-photocatalysis assessment has contributed to attaining higher dye degradation efficiency.

This manuscript includes all relevant data.

Xie, W. et al. Photocatalytic performance of Bi2VO5.5/Bi2O3 laminated composite films under simulated sunlight irradiation. Solid State Sci. 94, 1–7 (2019).

Article ADS CAS Google Scholar

Lv, T. et al. Facile synthesis of CdS/Bi4V2O11 photocatalysts with enhanced visible-light photocatalytic activity for degradation of organic pollutants in water. Dalt. Trans. 46, 12675–12682 (2017).

Article CAS Google Scholar

He, Y. et al. Efficient degradation of RhB over GdVO4/g-C3N4 composites under visible-light irradiation. Chem. Eng. J. 215, 721–730 (2013).

Article Google Scholar

Zhao, Y., Liu, X., Gu, S. & Liu, J. Enhanced photocatalytic performance of rhodamine B and enrofloxacin by Pt loaded Bi4V2O11: boosted separation of charge carriers, additional superoxide radical production, and the photocatalytic mechanism. RSC Adv. 11, 9746–9755 (2021).

Article ADS CAS PubMed PubMed Central Google Scholar

Nasuha, N., Hameed, B. H. & Din, A. T. M. Rejected tea as a potential low-cost adsorbent for the removal of methylene blue. J. Hazard. Mater. 175, 126–132 (2010).

Article CAS PubMed Google Scholar

Martin, M. J., Artola, A., Balaguer, M. D. & Rigola, M. Activated carbons developed from surplus sewage sludge for the removal of dyes from dilute aqueous solutions. Chem. Eng. J. 94, 231–239 (2003).

Article CAS Google Scholar

Ri, C.-N. et al. The synthesis of a Bi2MoO6/Bi4V2O11 heterojunction photocatalyst with enhanced visible-light-driven photocatalytic activity. RSC Adv. 8, 5433–5440 (2018).

Article ADS CAS PubMed PubMed Central Google Scholar

Vadivel, S. et al. Facile synthesis of novel CaFe2O4/g-C3N4 nanocomposites for degradation of methylene blue under visible-light irradiation. J. Colloid Interface Sci. 480, 126–136 (2016).

Article ADS CAS PubMed Google Scholar

Kumar, S. & Sahare, P. D. Photocatalytic activity of bismuth vanadate for the degradation of organic compounds. NANO 8, 1350007 (2013).

Article Google Scholar

Tantak, N. P. & Chaudhari, S. Degradation of azo dyes by sequential Fenton's oxidation and aerobic biological treatment. J. Hazard. Mater. 136, 698–705 (2006).

Article CAS PubMed Google Scholar

Laowansiri, S., Vinitnantharat, S., Chaiprasert, P. & Ha, S. R. Anaerobic degradation kinetics of reactive dye with different carbon sources. J. Environ. Biol. 29, 309 (2008).

CAS PubMed Google Scholar

Chandrasekaran, S. et al. Spinel photocatalysts for environmental remediation, hydrogen generation, CO2 reduction and photoelectrochemical water splitting. J. Mater. Chem. A 6, 11078–11104 (2018).

Article CAS Google Scholar

Liu, J. et al. Enhanced electron separation on in-plane benzene-ring doped g-C3N4 nanosheets for visible light photocatalytic hydrogen evolution. Appl. Catal. B Environ. 244, 459–464 (2019).

Article CAS Google Scholar

An, X., Hu, C., Liu, H. & Qu, J. Oxygen vacancy mediated construction of anatase/brookite heterophase junctions for high-efficiency photocatalytic hydrogen evolution. J. Mater. Chem. A 5, 24989–24994 (2017).

Article CAS Google Scholar

Lv, C. et al. Realizing nanosized interfacial contact via constructing BiVO4/Bi4V2O11 element-copied heterojunction nanofibres for superior photocatalytic properties. Appl. Catal. B Environ. 179, 54–60 (2015).

Article CAS Google Scholar

Di Paola, A., García-López, E., Marcì, G. & Palmisano, L. A survey of photocatalytic materials for environmental remediation. J. Hazard. Mater. 211, 3–29 (2012).

Article PubMed Google Scholar

Tang, J., Zou, Z. & Ye, J. Efficient photocatalytic decomposition of organic contaminants over CaBi2O4 under visible-light irradiation. Angew. Chemie 116, 4563–4566 (2004).

Article ADS Google Scholar

Chen, X., Liu, L., Yu, P. Y. & Mao, S. S. Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals. Science (80-) 331, 746–750 (2011).

Article ADS CAS Google Scholar

Chen, H., Nanayakkara, C. E. & Grassian, V. H. Titanium dioxide photocatalysis in atmospheric chemistry. Chem. Rev. 112, 5919–5948 (2012).

Article CAS PubMed Google Scholar

Li, Z. et al. Novel application of Ag/PbBiO2I nanocomposite in piezocatalytic degradation of rhodamine B via harvesting ultrasonic vibration energy. Ultrason. Sonochem. 78, 105729 (2021).

Article CAS PubMed PubMed Central Google Scholar

Tu, S. et al. Piezocatalysis and piezo-photocatalysis: catalysts classification and modification strategy, reaction mechanism, and practical application. Adv. Funct. Mater. 30, 1–31 (2020).

Article Google Scholar

Cao, S., Zhou, P. & Yu, J. Recent advances in visible light Bi-based photocatalysts. Chinese J. Catal. 35, 989–1007 (2014).

Article Google Scholar

Kako, T. & Ye, J. Photocatalytic decomposition of acetaldehyde over rubidium bismuth niobates under visible light irradiation. Mater. Trans. 46, 2694–2698 (2005).

Article CAS Google Scholar

Kumar, V. R., Prasad, V. S., Wariar, P. R. S. & Koshy, J. Synthesis, characterization and photocatalytic activities of Ba2YbZrO5.5 nanoparticles under solar irradiation. NANO 6, 279–286 (2011).

Article CAS Google Scholar

Ramachandran, R. et al. Photocatalytic properties of KBiO3 and LiBiO3 with tunnel structures. J. Chem. Sci. 123, 517–524 (2011).

Article CAS Google Scholar

Xie, W., Hu, W., Zou, L. & Bao, D. Enhanced photocatalytic activity and dielectric property of c-axis oriented Bi2VO5.5 thin film by Gd3+ doping. Ceram. Int. 41, S265–S273 (2015).

Article CAS Google Scholar

Guo, W., Fan, K., Zhang, J. & Xu, C. 2D/2D Z-scheme Bi2WO6/Porous-g-C3N4 with synergy of adsorption and visible-light-driven photodegradation. Appl. Surf. Sci. 447, 125–134 (2018).

Article ADS CAS Google Scholar

Naqvi, F. K., Faraz, M., Beg, S. & Khare, N. Synthesis and phase transformation studies of dysprosium-doped Bi4V2O11 nanoparticles and their application in visible light photocatalytic degradation of tetracycline drug. ACS Omega 3, 11300–11306 (2018).

Article CAS PubMed PubMed Central Google Scholar

Gao, X.-M., Fu, F. & Li, W.-H. Photocatalytic degradation of phenol over Cu loading BiVO4 metal composite oxides under visible light irradiation. Phys. B Condens. Matter 412, 26–31 (2013).

Article ADS CAS Google Scholar

Kumari, N., Krupanidhi, S. B. & Varma, K. B. R. Dielectric, impedance and ferroelectric characteristics of c-oriented bismuth vanadate films grown by pulsed laser deposition. Mater. Sci. Eng. B 138, 22–30 (2007).

Article CAS Google Scholar

Kumari, N., Krupanidhi, S. B. & Varma, K. B. R. Structural and electrical studies on Bi2VO5.5/Bi4Ti3O12 multilayer thin films. J. Mater. Sci. Mater. Electron. 22, 639–648 (2011).

Article CAS Google Scholar

de yDompablo, M. E. A., Garcia-Alvarado, F. & Moran, E. Bi4V2O11 and related compounds as positive electrode materials for lithium rechargeable batteries. Solid State Ion. 91, 273–278 (1996).

Article Google Scholar

Pookmanee, P., Intaphong, P., Phanmalee, J., Kangwansupamonkon, W. & Phanichphant, S. Characterization of bismuth vanadate nanopowder prepared by microwave method. in Materials Science Forum vol. 872, pp 253–257 (Trans Tech Publ, 2016).

Kumar, M. et al. Piezo-photocatalytic activity of Bi2VO5.5 for methylene blue dye degradation. J. Mater. Res. Technol 21, 1998–2012 (2022).

Article CAS Google Scholar

Pell, J. W., Ying, J. Y. & zur Loye, H.-C. Sol-gel synthesis of α-Bi2VO5.5 using a soluble bismuth precursor. Mater. Lett. 25, 157–160 (1995).

Article CAS Google Scholar

Vaidhyanathan, B., Ganguli, M. & Rao, K. J. Fast solid state synthesis of metal vanadates and chalcogenides using microwave irradiation. Mater. Res. Bull. 30, 1173–1177 (1995).

Article CAS Google Scholar

Joseph, M., Lee, H. Y., Tabata, H. & Kawai, T. Ferroelectric behavior of epitaxial Bi2VO5.5 thin films on Si (100) formed by pulsed-laser deposition. J. Appl. Phys. 88, 1193–1195 (2000).

Article ADS CAS Google Scholar

Kumari, N., Parui, J., Varma, K. B. R. & Krupanidhi, S. B. C-V studies on metal–ferroelectric bismuth vanadate (Bi2VO5.5)–semiconductor structure. Solid State Commun. 137, 566–569 (2006).

Article ADS CAS Google Scholar

Zhu, Q. et al. Efficient full spectrum responsive photocatalytic NO conversion at Bi2Ti2O7: Co-effect of plasmonic bi and oxygen vacancy. Appl. Catal. B Environ. 319, 121888 (2022).

Article CAS Google Scholar

Kumari, N., Krupanidhi, S. B. & Varma, K. B. R. Structural, ferroelectric and optical properties of Bi2VO5.5 thin films deposited on platinized silicon (100) Pt/TiO2/SiO2/Si substrates. Appl. Phys. A 91, 693–699 (2008).

Article ADS CAS Google Scholar

Paramesh, G., Kumari, N., Krupanidhi, S. B. & Varma, K. B. R. Large nonlinear refraction and two photon absorption in ferroelectric Bi2VO5.5 thin films. Opt. Mater. (Amst) 34, 1822–1825 (2012).

Article ADS CAS Google Scholar

Wang, J. M. et al. Synthesis of BiVO4/Bi2VO5.5 Heterogeneous nanostructures with enhanced visible light photocatalytic activity. in Materials Science Forum vol. 847, pp. 211–217 (Trans Tech Publ, 2016).

Castro, A., Millán, P., Ricote, J. & Pardo, L. Room temperature stabilisation of γ-Bi2VO5.5 and synthesis of the new fluorite phase f-Bi2VO5 by a mechanochemical activation method. J. Mater. Chem. 10, 767–771 (2000).

Article CAS Google Scholar

Kumar, M., Vaish, R. & ben Ahmed, S. Piezo-photocatalytic activity of mechanochemically synthesized BiVO4 for dye cleaning. J. Am. Ceram. Soc. 105(3), 2309–2322 (2022).

Article CAS Google Scholar

Luo, Q., Zhang, L., Chen, X., Tan, O. K. & Leong, K. C. Mechanochemically synthesized m-BiVO4 nanoparticles for visible light photocatalysis. RSC Adv. 6, 15796–15802 (2016).

Article ADS CAS Google Scholar

Guan, M.-L., Ma, D.-K., Hu, S.-W., Chen, Y.-J. & Huang, S.-M. From hollow olive-shaped BiVO4 to n− p core− shell BiVO4@ Bi2O3 microspheres: Controlled synthesis and enhanced visible-light-responsive photocatalytic properties. Inorg. Chem. 50, 800–805 (2011).

Article CAS PubMed Google Scholar

Phanmalee, J., Intaphong, P., Kangwansupamonkon, W., Phanichphant, S. & Pookmanee, P. The Photocatalytic degradation of methylene blue using bismuth vanadate (Bi2VO5.5) Powder. in Key Engineering Materials vol. 751 707–712 (Trans Tech Publ, 2017).

Xie, W., Qin, N., Li, B. & Bao, D. Enhanced visible-light catalytic activity of Au nanoparticles loaded c-axis oriented Bi2VO5.5 porous thin films. Ceram. Int. 41, 8433–8443 (2015).

Article CAS Google Scholar

Ebrahimi-Purkani, A. & Kashani-Bozorg, S. F. Nanocrystalline Mg2Ni-based powders produced by high-energy ball milling and subsequent annealing. J. Alloys Compd. 456, 211–215 (2008).

Article CAS Google Scholar

Zhang, D. et al. Facile in situ chemical transformation synthesis, boosted charge separation, and increased photocatalytic activity of BiPO4/BiOCl pn heterojunction photocatalysts under simulated sunlight irradiation. J. Phys. Chem. Solids 147, 109630 (2020).

Article CAS Google Scholar

Nabi, G., Malik, N. & Raza, W. Degradation effect of temperature variation and dye loading g-C3N4 towards organic dyes. Inorg. Chem. Commun. 119, 108050 (2020).

Article CAS Google Scholar

Patwe, S. J. et al. Probing the local structure and phase transitions of Bi4V2O11-based fast ionic conductors by combined raman and XRD studies. J. Am. Ceram. Soc. 96, 3448–3456 (2013).

Article CAS Google Scholar

Dimitrov, V., Dimitriev, Y. & Montenero, A. IR spectra and structure of V2O5 GeO2 Bi2O3 glasses. J. Non. Cryst. Solids 180, 51–57 (1994).

Article ADS CAS Google Scholar

Abd El-Moneim, A. DTA and IR absorption spectra of vanadium tellurite glasses. Mater. Chem. Phys. 73, 318–322 (2002).

Article CAS Google Scholar

Tripathy, D., Saikia, A., Tado, G. T. & Pandey, A. Dielectric study of Ti-doped Bi2VO5.5 solid electrolyte. Indian J. Phys. 93, 845–859 (2019).

Article ADS CAS Google Scholar

Tripathy, D., Saikia, A. & Pandey, A. Effect of simultaneous Ti and Nb doping on structure and ionic conductivity of Bi2V1−xTix/2Nbx/2O5.5−δ (0.1≤ x≤ 0.25) ceramics. Ionics 25, 2221–2230 (2019).

Article CAS Google Scholar

Lv, C. et al. Oxygen-induced Bi5+-self-doped Bi4V2O11 with ap–n homojunction toward promoting the photocatalytic performance. ACS Appl. Mater. Interfaces 9, 23748–23755 (2017).

Article CAS PubMed Google Scholar

Liu, Z., Niu, J., Feng, P., Sui, Y. & Zhu, Y. One-pot synthesis of Bi24O31Br 10/Bi4V2O11 heterostructures and their photocatalytic properties. RSC Adv. 4, 43399–43405 (2014).

Article ADS CAS Google Scholar

Anwar, K., Naqvi, F. K. & Beg, S. Synthesis of tetragonally stabilized lanthanum doped bismuth vanadium oxide nanoparticles and its enhanced visible light induced photocatalytic performance. Phase Trans. 95, 64–79 (2022).

Article CAS Google Scholar

Daelman, N. et al. Quasi-degenerate states and their dynamics in oxygen deficient reducible metal oxides. J. Chem. Phys. 152, 50901 (2020).

Article CAS Google Scholar

Fan, C.-M. et al. Synproportionation reaction for the fabrication of Sn2+ self-doped SnO2-x nanocrystals with tunable band structure and highly efficient visible light photocatalytic activity. J. Phys. Chem. C 117, 24157–24166 (2013).

Article CAS Google Scholar

Xia, J. et al. Highly monodisperse Cu3Mo2O9 micropompons with excellent performance in photocatalysis, photocurrent response and lithium storage. RSC Adv. 5, 12015–12024 (2015).

Article ADS CAS Google Scholar

Kumar, M., Singh, G. & Vaish, R. Reduced graphene oxide/bismuth vanadate composite as an efficient piezocatalyst for degradation of organic dye. Mater. Adv 2(12), 4093–4101 (2021).

Article CAS Google Scholar

Singh, K. P., Singh, G. & Vaish, R. Utilizing the localized surface piezoelectricity of centrosymmetric Sr1-xFexTiO3 (x≤ 0.2) ceramics for piezocatalytic dye degradation. J. Eur. Ceram. Soc. 41, 326–334 (2021).

Article CAS Google Scholar

Ghows, N. & Entezari, M. H. Kinetic investigation on sono-degradation of Reactive Black 5 with core–shell nanocrystal. Ultrason. Sonochem. 20, 386–394 (2013).

Article CAS PubMed Google Scholar

Tezcanli-Güyer, G. & Ince, N. H. Individual and combined effects of ultrasound, ozone and UV irradiation: A case study with textile dyes. Ultrasonics 42, 603–609 (2004).

Article PubMed Google Scholar

Morris, M. R., Pendlebury, S. R., Hong, J., Dunn, S. & Durrant, J. R. Effect of internal electric fields on charge carrier dynamics in a ferroelectric material for solar energy conversion. Adv. Mater. 28, 7123–7128 (2016).

Article CAS PubMed Google Scholar

Yang, W. et al. Ferroelectric polarization-enhanced photoelectrochemical water splitting in TiO2–BaTiO3 core–shell nanowire photoanodes. Nano Lett. 15, 7574–7580 (2015).

Article ADS CAS PubMed Google Scholar

Yang, Q., Wang, W., Xu, S. & Wang, Z. L. Enhancing light emission of ZnO microwire-based diodes by piezo-phototronic effect. Nano Lett. 11, 4012–4017 (2011).

Article ADS CAS PubMed Google Scholar

Singh, G., Kumar, M. & Vaish, R. Promising multicatalytic and adsorption capabilities in V2O5/BiVO4 composite pellets for water-cleaning application. Surf. Interfaces 23, 100924 (2021).

Article CAS Google Scholar

Singh, R. P. et al. Synthesis of Ag2V4O11 nanoflakes mediated photoactivation of peroxymonosulfate ion for enhanced dye degradation and intrinsic bactericidal activity. Mater. Sci. Semicond. Process. 143, 106526 (2022).

Article CAS Google Scholar

Kumar, M. et al. Sonophotocatalytic dye degradation using rGO-BiVO4 composites. Glob. Chall. 6(6), 2100132 (2022).

Article MathSciNet PubMed PubMed Central Google Scholar

Priac, A., Badot, P.-M. & Crini, G. Treated wastewater phytotoxicity assessment using Lactuca sativa: Focus on germination and root elongation test parameters. C. R. Biol. 340, 188–194 (2017).

Article PubMed Google Scholar

Singh, A., Bhati, A., Khare, P., Tripathi, K. M. & Sonkar, S. K. Soluble graphene nanosheets for the sunlight-induced photodegradation of the mixture of dyes and its environmental assessment. Sci. Rep. 9, 1–12 (2019).

ADS Google Scholar

Emino, E. R. & Warman, P. R. Biological assay for compost quality. Compost Sci. Util. 12, 342–348 (2004).

Article Google Scholar

Kumar, A. & Pandey, G. A review on the factors affecting the photocatalytic degradation of hazardous materials. Mater. Sci. Eng. Int. J 1, 1–10 (2017).

CAS Google Scholar

Zhao, Z. et al. Exclusive enhancement of catalytic activity in Bi0.5Na0.5TiO3 nanostructures: new insights into the design of efficient piezocatalysts and piezo-photocatalysts. J. Mater. Chem. A 8, 16238–16245 (2020).

Article CAS Google Scholar

Zhu, Q. et al. Polarization-enhanced photocatalytic activity in non-centrosymmetric materials based photocatalysis: A review. Chem. Eng. J. 426, 131681 (2021).

Article CAS Google Scholar

Feng, W. et al. Hydrogenated TiO2/ZnO heterojunction nanorod arrays with enhanced performance for photoelectrochemical water splitting. Int. J. Hydrog. Energy 42, 3938–3946 (2017).

Article CAS Google Scholar

Zhu, L., Meng, Z.-D., Park, C.-Y., Ghosh, T. & Oh, W.-C. Characterization and relative sonocatalytic efficiencies of a new MWCNT and CdS modified TiO2 catalysts and their application in the sonocatalytic degradation of rhodamine B. Ultrason. Sonochem. 20, 478–484 (2013).

Article CAS PubMed Google Scholar

Lei, H. et al. Synergetic photocatalysis/piezocatalysis of bismuth oxybromide for degradation of organic pollutants. J. Alloys Compd. 809, 151840 (2019).

Article CAS Google Scholar

Ganeshbabu, M. et al. Synthesis and characterization of BiVO4 nanoparticles for environmental applications. RSC Adv. 10, 18315–18322 (2020).

Article ADS CAS PubMed PubMed Central Google Scholar

Lin, E. et al. Enhanced piezocatalytic, photocatalytic and piezo-/photocatalytic performance of diphasic Ba1−xCaxTiO3 nanowires near a solubility limit. Catal. Sci. Technol. 9, 6863–6874 (2019).

Article CAS Google Scholar

Zhou, X. et al. Excellent catalytic performance of molten-salt-synthesized Bi0.5Na0.5TiO3 nanorods by the piezo-phototronic coupling effect. Nano Energy 84, 105936 (2021).

Article CAS Google Scholar

Zhang, C. et al. pn Heterojunction of BiOI/ZnO nanorod arrays for piezo-photocatalytic degradation of bisphenol A in water. J. Hazard. Mater. 399, 123109 (2020).

Article CAS PubMed Google Scholar

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This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20192010106790 and No. 20204010600090). The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University, Saudi Arabia for funding this work through Large Research Groups Program under Grant Number L.R.G.P2/274/44.

School of Engineering, Indian Institute of Technology Mandi, Mandi, Himachal Pradesh, 175005, India

Manish Kumar & Rahul Vaish

Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, Saudi Arabia

Imen Kebaili & Imed Boukhris

Department of Electrical Engineering, Hanyang University, 222, Wangsimni-ro, Seongdong-gu, Seoul, 04763, Korea

Hyeong Kwang Benno Park, Yun Hwan Joo & Tae Hyun Sung

Center for Creative Convergence Education, Hanyang University, 222, Wangsimni-ro, Seongdong-gu, Seoul, 04763, Korea

Anuruddh Kumar

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M.K. designed the research, conducted the experiments, and prepared the manuscript and rest of the authors R.V., I.K., I.B., H.P., Y.J.,T.S. and A.K. have reviewed/edited the manuscript.

Correspondence to Anuruddh Kumar.

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Kumar, M., Vaish, R., Kebaili, I. et al. Ball-milling synthesized Bi2VO5.5 for piezo-photocatalytic assessment. Sci Rep 13, 8188 (2023). https://doi.org/10.1038/s41598-023-33658-2

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Received: 02 February 2023

Accepted: 17 April 2023

Published: 20 May 2023

DOI: https://doi.org/10.1038/s41598-023-33658-2

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